Diplomarbeit:
Untersuchungen zur enantioselektiven Synthese chiraler helicaler Kupfer-(II)-Koordinationspolymere

Doktorarbeit:
1D-/ 2D-Koordinationspolymere und metalla-Phane: Aufbau und Strukturaufklärung

aktuelles Projekt:
Bicyclische Metallacryptate

Wissenschaftliche Veröffentlichungen:

1. Molecular Architectures
   R. W. Saalfrank, A. Dresel, B. Hörner, O. Struck, H. Maid, Mol. Cryst. Liq. Cryst. 1994, 240, 39-52.

2. 1D- and 2D-Coordination Polymers from Self-Complementary Building Blocks: Co-Crystallization of (P)- and (M)-Single-Stranded Diastereoisomers
   R. W. Saalfrank, H. Maid, F. Hampel, K. Peters, Eur. J. Inorg. Chem. 1999 1859-1867.

3. A Meso-helical Coordination Polymer from Achiral Dinuclear [Cu2(H3CCN)2(mü-pydz)3][PF6]2 and 1,3-Bis(diphenylphosphanyl)propane - Synthesis and Crystal Structure of of {[Cu(mü-pydz)2][PF6]}
   L. Plasseraud, H. Maid, F. Hampel, R. W. Saalfrank, Chem. Eur. J.,2001,7,4007-4011.

4. Durch Selbstorganisation zu hybriden Metallacoronaten oder eindimensionalen, oxoverbrückten Metallsträngen - Koordinationszahl-gesteuerte Produktbildung
   R. W. Saalfrank, H. Maid, N. Mooren, F. Hampel, Angew. Chem. 2002, 114, 323-326; Angew. Chem. Int. Ed. Engl. 2002, 41 , 304-307.
5. Enantiomerisation of Tetrahedral Homochiral [M₄L₆ ] Clusters: Synchronized Four Bailar Twists and Six Atropenantiomerisation Processes Monitored by Temperature-Dependent Dynamic ¹H NMR Spectroscopy
   Rolf W. Saalfrank, Bernhard Demleitner, Horst Glaser, Harald Maid, Daniela Bathelt, Frank H ampel, Walter Bauer, Markus Teichert Chem. Eur. J., 2002, 8, 2679-2683.
6. Synthesis of Tetrahemispheraplexes with Ammonium, Alkylammonium or Alkaline M etal Ions as Exohedral Guests via Self-Assembly or Guest Exchange
   Rolf W. Saalfrank, Bernhard Demleitner, Horst Glaser, Harald Maid, Stefan Reihs, Walter Bauer, Monica Maluenga, Frank Hampel, Markus Teichert, Harald Krautscheid Eur. J. Inorg. Chem. , 2003, 6, 822-829, 1253-1254.
7. Synthesis, Structure, and Dynamics of Six-Membered Metallacoronands and Metallodendrimers of Iron and Indium
   Rolf W. Saalfrank, Christian Deutscher, Harald Maid, Ayuk M. Ako, Stefan Sperner, Takayuki Nakajima, Walter Bauer, Frank Hampel, Bernd A. Heß, Nico J. R. van Eikema Hommes, Ralph Puchta, Frank W. Heinemann Chem. Eur. J., 2004, 10, 1899-1905.
8. Syntheses and Properties of Metal-Centered Mixed-Valent [NEt₄]{Mn^II[Mn^II₃Mn^III3Cl₆(L)₆]} Manganese Wheels
   Rolf W. Saalfrank, Takayuki Nakajima, Nicolai Mooren, Andreas Scheurer, Harald Maid, Frank Hampel, Christian Trieflinger, Jörg Daub Eur. J. Inorg. Chem. , 2005,8, 1149-1153.
   

9. Trinuclear Oxo-Centered Iron and Iron/Nickel Clusters - Ligand-Controlled Homo/Hetero Valency
   Rolf W. Saalfrank, Andreas Scheurer, Klaus Pokorny, Harald Maid, Uwe Reimann, Frank Hampel, Frank W. Heinemann, Volker Schünemann, Alfred X. Trautwein Eur. J. Inorg. Chem., 2005, 1383-1387.
   

10. Influence of the Conformation of Salen Complexes on the Stereochemistry of the Asymmetric Epoxidation of Olefins
    Andreas Scheurer, Harald Maid, Frank Hampel, Rolf W. Saalfrank, Loic Toupet, Paul Mosset, Ralph Puchta, Nico J. R. van Eikema Hommes Eur. J. Org. Chem., 2005, 2566-2574.
    

11. Metal-Organic Coordination Networks of Ferric Wheels, their Surface-supported Supramolecular Architectures and STM/STS Imaging
    Ayuk M. Ako, Harald Maid, Stefan Sperner, Syeda Huma H. Zaidi, Rolf W. Saalfrank, Mohammad S. Alam, Paul Müller, Frank W. Heinemann, Supramolecular Chemistry, 2005, 17, 315 - 321.
    

12. Roots: From carbenes to allenes and coordination polymers
    Ever present never twice the same
    R. W. Saalfrank, H. Maid, Chem. Comm., 2005, 48, 5953-5967.

13. Enantiomerenreine Kupfer(II)-Cubankomplexe [Cu₄L₂(OMe)₄] aus chiralen Bis-1,3-diketonen H₂L durch diastereoselektive Selbstorganisation
    R. W. Saalfrank, C. Schmidt, H. Maid, F. Hampel, W. Bauer, A. Scheurer, Angew. Chem. 2006, 118, 322-325; Angew. Chem. Int. Ed. 2006, 45 , 315-318.
14. Synthesis and Characterization of Metal-Centered, Six-Membered, Mixed- Valent, Heterometallic Wheels of Iron, Manganese, and Indium
    Rolf W. Saalfrank, Raju Prakash, Harald Maid, Frank Hampel, Frank W. Heinemann, Alfred X. Trautwein, Lars H. Böttger Chem. Eur. J., 2006, 12 , 2428 – 2433.
15. Synthese und Redoxeigenschaften gemischtvalenter achtkerniger Eisendefekthexacubane und eines (CaCl)-überdachten raumzentrierten Eisen(III)-Sechsflächners
    R. Prakash, R. W. Saalfrank, H. Maid, A. Scheurer, F. W. Heinemann, A. X. Trautwein, L. H. Böttger, Angew. Chem.,2006, 118, 6017-6022; Angew. Chem. Int. Ed., 2006, 45 , 5885-5889.
16. Auffädelung von Caesiumionen: Metall-, Gast- und Ligandenkontrolle in der supramolekularen Koordinationschemie
    R. W. Saalfrank, A. Scheurer, R. Puchta, F. Hampel, H. Maid, F. W. Heinemann, Angew. Chem.,2007, 119, 269-272; Angew. Chem. Int. Ed., 2007, 46, 265-268.
17. Synthesis and Structure of Self-Complementary {2}-Metallacryptates and Their Linear or Meandering Infinite Arrangements in the Solid State
    R. W. Saalfrank, N. Mooren, A. Scheurer, H. Maid, F. W. Heinemann, F. Hampel, W. Bauer, Eur. J. Inorg. Chem.,2007, 4815-4822.
18. Enantiospecific Syntheses of Copper Cubanes, Double-Stranded Copper/Palladium Helicates, and a (Dilithium)–Dinickel Coronate from Enantiomerically Pure Bis-1,3-diketones—Solid-State Self-Organization Towards Wirelike Copper/Palladium Strands
    R. W. Saalfrank, C. Spitzlei, A. Scheurer, H. Maid, F. W. Heinemann, F. Hampel, Chem. Eur. J., 2008, 14, 1472-1481.

19. Supramolekulare Koordinationschemie - Synergie von Zufallsentdeckung und rationalem Design
    R. W. Saalfrank, H. Maid, A. Scheurer, Angew. Chem., 2008, 120, 8924-8956; Angew. Chem. Int. Ed., 2008, 47, 8794-8824.
20. Template and pH-Mediated Synthesis of Tetrahedral Indium Complexes [Cs in {In₄(L)₄}]⁺ and [In₄(H^NL)₄]⁴⁺: Breaking the Symmetry of N-Centered C₃ (L)^3- to Give Neutral [In₄(L)₄]
    R. W. Saalfrank, H. Maid, A. Scheurer, F. W. Heinemann, R. Puchta, W. Bauer, D. Stern, D. Stalke, Angew. Chem., 2008, 120, 9073-9077; Angew. Chem. Int. Ed., 2008, 47, 8941-8945.
21. Dinukleare cofaciale Metallocyclen mit Kupfer und Nickel: Synthese und Struktur
    W. Bauer, F. Hampel, H. Maid, Z. Naturforsch., 2010, 65b, 273-280.
22. Dynamic Phenomena in Self-Complementary {2}-Metallocryptates Probed by Solution ¹³³Cs-NMR. New Insights Into Ion Pairing Processes. X-Ray Structure and Solid State NMR Spectra of a Meandering Species
    H. Maid, F. W. Heinemann, A. Scheurer, N. Mooren, R. W. Saalfrank, W. Bauer, Helv. Chim. Acta 2012, 95, 2429-2445.