Diplomarbeit:
Thema...

Doktorarbeit:
Synthesis, Structure and Reactivity of Novel Heterometallic Complexes Bearing hapto⁵-Cyclopentadienyl Anciallary Ligands

aktuelles Projekt:
Metallawheels

Wissenschaftliche Veröffentlichungen:

1. Preparation and structurRe of the First Ansa-Molybdenocene and tungstenocene derivatives. Reaktion of [O(SiMe₂C₅H₄)₂]MoH₂ with Methyl Methacrylate to Prove the Olefine Attacking Site.
   T. Mise, M. Maeda, T. Nakajima, I. Shimizu, Y. Yamamoto, Y. Wakatsuki, J. Organomet. Chem. 1994, 473, 155-162.

2. A Photochemical Route to Heterometallic Complexes - Synthesis and Structural Characterization of Dinuclear and Trinuclear Complexes Having a Molybdenoeene or Tungstenocene Unit
   T. Nakajima, T. Mise, K. Kobayashi, Y. Wakatsuki, Organometallics 1995, 14, 5598-5604.

3. Facile synthesis of keto nitriles by Cu(II)-promoted photooxidative cleavage of cyclic olefins
   I. Shimizu, M. Fujita, T. Nakajima, T. Satoh, Chem. Lett. 1997, 887.

4. Molybdenum-catalyzed aromatic substitution with olefins and alcohols
   I. Shimizu, M. Fujita, T. Nakajima, A. Yamamoto, Chem. Lett. 1997, 851-852.

5. Facile P-C bond cleavage of trimethylphosphine at a heterodimetallic (Ni-W) center
   T. Nakajima, I. Shimizu, K. Kobayashi, H. Koshino, Y. Wakatsuki, Inorg. Chem. 1997, 6440-6442.

6. Synthesis of triangular and tetrahedral heteronuclear metal clusters using hydride complexes of cyclopentadienylrhodium and -ruthenium as the precursors
   T. Nakajima, I. Shimizu, K. Kobayashi, Y. Wakatsuki, Organometallics 1998, 17, 262-269.

7. Synthese vielkerniger gemischtmetallischer Cluster durch Verknüpfung anionischer Ruthenium-Carbido-Cluster über Palladiumeinheiten
   T. Nakajima, A. Ishiguro, Y. Wakatsuki, Angew. Chem. 2000, 112, 1175-1177; Angew. Chem. Int. Ed. Engl. 2000, 39, 1131-1134.
   

8. Molekulare Super-Drähte durch Selbstorganisation von Übergangsmetall-Clusteranionen und Metallkationen
   T. Nakajima, A. Ishiguro, Y. Wakatsuki, Angew. Chem. 2001, 113, 1096-1099; Angew. Chem. Int. Ed. Engl. 2001, 40, 1066-1068.
   

9. Self-assembly and crystal structure of a novel hetero-octametallic molecular box (Chelate complexes, Parti 23)
   R. W. Saalfrank, I. Bernt, F. Hampel, A. Scheurer, T. Nakajima, S. H. Z. Huma, F. W. Heinemann, M. Schmidtmann, A. Müller, Polyhedron , 2003, 22, 2985-2989.

10. Synthesis, Structure, and Dynamics of Six-Membered Metallacoronands and Metallodendrimers of Iron and Indium
    Rolf W. Saalfrank, Christian Deutscher, Harald Maid, Ayuk M. Ako, Stefan Sperner, Takayuki Nakajima, Walter Bauer, Frank Hampel, Bernd A. Heß, Nico J. R. van Eikema Hommes, Ralph Puchta, Frank W. Heinemann Chem. Eur. J., 2004, 10 , 1899-1905.


11. Six-Membered Metalla-coronands. Synthesis and Crystal Packing: Columns, Compartments, and 3D-Networks
    Rolf W. Saalfrank, Christian Deutscher, Stefan Sperner, Takayuki Nakajima, Ayuk M. Ako, Eveline Uller, Frank Hampel, Frank W. Heinemann Inorg. Chem. 2004,43, 4372-4382.
    

12. Syntheses and Properties of Metal-Centered Mixed-Valent [NEt₄]{Mn^II[Mn^II₃Mn^III3Cl₆(L)₆]} Manganese Wheels
    Rolf W. Saalfrank, Takayuki Nakajima, Nicolai Mooren, Andreas Scheurer, Harald Maid, Frank Hampel, Christian Trieflinger, Jörg Daub Eur. J. Inorg. Chem. , 2005,8, 1149-1153.
    

13. Synthesis, Redox, and Magnetic Properties of a Neutral, Mixed-Valent Heptanuclear Manganese Wheel with S = 27/2 High-Spin Ground State
    R. W. Saalfrank, A. Scheurer, R. Prakash, F. W. Heinemann, T. Nakajima, F. Hampel, R. Leppin, B. Pilawa, H. Rupp, P. Müller, Inorg. Chem., 2007, 46, 1586-1592.